I applied.
As someone else teased, I need a distraction from shopping, but in all seriousness I think it's a great idea to allow others a chance in their spare time to contribute to our virtual world and help others feel more comfortable in learning what it's about, how to get started, etc. The possibilities are endless here on Second Life--there's so much you can do and it's extremely overwhelming. I did a lot of research on my own to get accustom to the controls and customizing my avatar (but I also have a technical background), but there were times I got really frustrated with scenarios that were very unique and if it weren't for a few key people I met that gave advice at the time, I might not still be around.
I'm curious, though, how many volunteers they're looking to select, and what the criteria for the screening process is. Also, when might those inquiring receive a response? If there are classes, I'm assuming most people have a valid chance of getting to try it out as long as they attend, do a good job, and follow the guidelines, but I don't know.
I do agree that a community "Group Chat" with mentors would be a nice addition. In my opinion, that would be perfect and easy to maintain, plus it would allow more freedom for everyone to assist whenever they want/can as they're doing other things in-world.